Basic
Principles - Thermodynamics
One can use thermodynamics, e.g. Pourbaix or E-pH diagrams, to
evaluate the theoretical activity of a given metal or
alloy provided the
chemical make-up of the environment is known. But for practical situations, it
is important to realize that the environment is a variable that can change with
time and conditions. It is also important to realize that the environment that
actually affects a metal corresponds to the micro-environmental conditions this
metal really 'sees', i.e. the local environment at the surface of the metal ...
and much more!!
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