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You are here: Home > Handbook > Periodic Table of Elements > Electron Orbits


The orbitals occupied by electrons in different subshells differ from each other with regard to their size, shape, and orientation in space. The larger the number of the principal shell, the greater the volume of the corresponding orbital.

For example, a 2s electron has an orbital of greater volume than a 1s electron. However, the orbitals of the higher principal shells overlap those of lower shells. This means that the outer electrons penetrate the regions occupied by inner electrons.

The shape of an s electron orbital is spherical while that of a p electron orbital is dumbbell shaped.

The number of possible orientations of atomic orbitals in space depends to an extent on the shape of the orbital. An s orbital still presents the same appearance to an outside observer since its shape is that of a sphere. Therefore an s orbital is said to be spherically symmetrical and without directional characteristics.

s_orbit.gif - 1.2 K
s orbitals


It is a bit more complex with p orbitals which occur in sets of three. It is not possible to determine the direction of any one orbital in a given set. However, the axes along which the three p orbitals lie are mutually at right angles to each other. The three p orbitals are designated as px, py and pz to emphasize their directional nature.


px_orbit.gif - 1.2 K
px
py_orbit.gif - 1.2 K
py
pz_orbit.gif - 1.2 K
pz

The five d orbitals consist of lobe-shaped regions arranged in space as shown below. The drawings are oriented so that the lobes of the orbitals designated dz2 and dx2-y2 lie along the axes and the lobes of the dxz, dyz, and dxy lie in between the axes.


dz2_orbit.gif - 1.2 K
dz2
dx2y2_orbit.gif - 1.2 K
dx2-y2
dxz_orbit.gif - 1.3 K
dxz
dyz_orbit.gif - 1.3 K
dyz
dxy_orbit.gif - 1.2 K
dxy

The seven f orbitals are not understood well enough to have agreement on their orientation in space. Their directional characteristics are too complex to be shown.



Related Links:
Periodic Table
Terminology
Periodic Law
> Electron Orbits
Electron Shells
Electron Subshells
Metals
Alkali Metals
Transition Metals
Non-Metals
Halogens
Noble Gases
Rare Earth Metals
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