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Astatine


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Seldom found in nature.
Atomic Number:85Atomic Symbol:At
Atomic Weight:210Electron Configuration:2-8-18-32-18-7
Shells:2,8,18,32,18,7Filling Orbital:6p5
Melting Point:302oCBoiling Point:337oC
Description:Radioactive member of the halogen group.
Uses:Does not occur in nature. Similar to iodine.
Produced by bombarding bismuth with alpha particles.

History

(Gr. astatos, unstable) Synthesized in 1940 by D.R. Corson, K.R. MacKenzie, and E. Segre at the University of California by bombarding bismuth with alpha particles.

Isotopes

The longest-lived isotopes, with naturally occurring uranium and thorium isotopes, and traces of 217At are equilibrium with 233U and 239Np reulting from interation of thorium and uranium with naturally produced neutrons.

Occurence

The total amount of astatine present in the earth's crust, however, is less than 1 oz.

Properties

  • Astatine can be produced by bombarding bismuth with energetic alpha particles to obtain the relatively long-lived 209-211At, which can be distilled from the target by heating in air.
  • The "time of flight" mass spectrometer has been used to confirm that this highly radioactive halogen behaves chemically very much like other halogens, particularly iodine.
  • Astatine is said to be more metallic than iodine, and, like iodine, it probably accumulates in the thyroid gland.

Uses

Workers at the Brookhaven National Laboratory have recently used reactive scattering in crossed molecular beams to identify and measure elementary reactions involving astatine.

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